全文获取类型
收费全文 | 728篇 |
免费 | 5篇 |
国内免费 | 20篇 |
专业分类
化学 | 598篇 |
力学 | 5篇 |
数学 | 61篇 |
物理学 | 89篇 |
出版年
2021年 | 3篇 |
2020年 | 1篇 |
2019年 | 9篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 16篇 |
2015年 | 12篇 |
2014年 | 19篇 |
2013年 | 26篇 |
2012年 | 26篇 |
2011年 | 53篇 |
2010年 | 54篇 |
2009年 | 56篇 |
2008年 | 36篇 |
2007年 | 71篇 |
2006年 | 41篇 |
2005年 | 42篇 |
2004年 | 50篇 |
2003年 | 28篇 |
2002年 | 19篇 |
2001年 | 12篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 10篇 |
1997年 | 5篇 |
1996年 | 16篇 |
1995年 | 24篇 |
1994年 | 14篇 |
1993年 | 23篇 |
1992年 | 8篇 |
1991年 | 13篇 |
1990年 | 11篇 |
1989年 | 9篇 |
1988年 | 8篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
排序方式: 共有753条查询结果,搜索用时 118 毫秒
71.
Shape verification aimed for manufacturing process control 总被引:1,自引:0,他引:1
72.
Luis A. Escudero Luis D. Martinez José A. Salonia José A. Gasquez 《Microchemical Journal》2010,95(2):164-168
An on-line zinc preconcentration and determination system implemented with inductively coupled plasma optical emission spectrometry (ICP-OES) was developed. The zinc was precipitated and retained on a minicolumn filled with ethyl vinyl acetate (EVA) at pH 9.0, without using any complexing reagent. The zinc ions were eluted from the minicolumn with 10% (v/v) hydrochloric acid. Experimental conditions including pH and sample loading and eluting variables were evaluated and established.An enrichment factor (EF) of 44 was obtained for Zn2+ with a preconcentration time of 120 s. Under the optimal conditions, the value of the limit of detection (3σ) for the preconcentration of 10 mL of sample was 0.08 μg L− 1. The sampling frequency was about 24 h− 1. The precision for six replicate determinations (repeatability conditions) at 50 μg L− 1 Zn level was 3.94% relative deviation standard (RSD), calculated from the peak heights obtained. The methodology was successfully applied to the determination of zinc in tap water samples and in a certified VKI reference material QC Metal LL1 DHI (Water & Environment) Denmark. 相似文献
73.
Zaifang Zhu Ximin Zhou Na Yan Lei Zhou Xingguo Chen 《Journal of chromatography. A》2010,1217(11):1856-1861
In order to improve the sensitivity of capillary electrophoresis (CE) and overcome the deficiency of commercial CE instruments in handling complex matrices directly, we proposed a novel technique which combined single-drop liquid–liquid–liquid microextraction (SD-LLLME) with CE on-line. In this technique, SD-LLLME was realized using a commercial CE instrument and, to further concentrate the target analyte, large-volume sample stacking combined sweeping without polarity switching was utilized. Even though without agitating the donor phase in the extraction process, the model compound, adenine was enriched 550-fold in only 10 min. The enrichment factors were 760 and 1030 when the extraction time was extended to 30 and 60 min, respectively. The relative standard deviations (RSDs) of adenine were 5.24% and 2.29% for peak area and migration time, respectively, which indicated that this method was much more reproducible compared to the existing methods that combined sample-preparation strategies with CE. In addition, this approach was selective while cleaning up target analyte. These mentioned advantages allowed the developed method to be an attractive approach to determining trace target compounds in complex real samples. 相似文献
74.
P‖Cmin随机算法研究 总被引:2,自引:0,他引:2
本文研究了P‖Cmin的随机算法及其最坏情况界,我们给出了Pm‖Cmin在线排序问题新的随机上界,并给出了P2‖Cmin的最好随机算法,其最坏情况界为2/3。对P2‖Cmin已知工件加工时间递减半在线模型,我们给出了一最坏情况界为6/7的随机算法并证明了它为最好的。 相似文献
75.
76.
天然水中微量稀土元素镧的流动注射在线预浓集ICP光谱法测定 总被引:1,自引:0,他引:1
本文采用P507萃淋树脂为固定相,应用流动注射(FI)在线预浓集技术,建立了镧的ICP发射光谱分析方法,对天然水中的微量镧进行了测定,获得满意结果。 相似文献
77.
78.
Marcos Tascon Fernando Benavente Victoria Sanz-Nebot Leonardo G. Gagliardi 《Analytica chimica acta》2015
A novel high performance system to control the temperature of the microcartridge in on-line solid phase extraction capillary electrophoresis (SPE–CE) is introduced. The mini-device consists in a thermostatic bath that fits inside of the cassette of any commercial CE instrument, while its temperature is controlled from an external circuit of liquid connecting three different water baths. The circuits are controlled from a switchboard connected to an array of electrovalves that allow to rapidly alternate the water circulation through the mini-thermostatic-bath between temperatures from 5 to 90 °C. The combination of the mini-device and the forced-air thermostatization system of the commercial CE instrument allows to optimize independently the temperature of the sample loading, the clean-up, the analyte elution and the electrophoretic separation steps. 相似文献
79.
A new indirect IC-ICP-MS method for the determination of aminopolycarboxylic acids in water samples is described. It is based on the addition of an excess of Pd(II) to water samples. The analytes are forced into very strong and negatively charged palladium complexes, separated by ion exchange chromatography and detected by their palladium content, utilizing an on-line coupled ICP-MS. This method is suitable to determine the concentration of 8 aminopolycarboxylic acids (nitrilotriacetic acid (NTA), (2-carboxyethyl) iminodiacetic acid (β-ADA), methylglycinediacetic acid (MGDA), 2-hydroxyethyl) ethylenediamine triacetic acid (HEDTA), diethylene triamine pentaacetic acid (DTPA), ethylendiamine tetraacetic acid (EDTA), 1,3-diaminopropane tetraacetic acid (1,3-PDTA) and 1,2-diaminopropane tetraacetic acid (1,2-PDTA) at the ng kg−1 level. The method is faster and easier than the established gas chromatography (GC)-method ISO 16588:2002 [1] and up to two orders of magnitude more sensitive than the ion pair chromatography based method of DIN 38413-8. Analytic performance is superior to ISO 16588:2002 and the comparability is good. 相似文献
80.
An on-line solid phase extraction-high performance liquid chromatography-tandemmass spectrometry method for the analysis of perfluoroalkyl substances (PFASs) in water samples was developed. The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column, sample loading rate and loading volume, and the concentration of ammonium acetate in mobile phase. Under the optimal condition, the analytical method displayed good linearity (r2 > 0.99) for 12 PFASs (C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids) over a concentration range of 0.5-100 ng/L. The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations (RSD) of five consecutive analyses were less than 10% for 1 ng/L standard solution. Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples. The recoveries of all perfluoroalkyl substances were in a range of 73%-117% when the sampleswere spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L. 相似文献